Given the tabulated data, calculate Δ S vap for each of the first four liquids. ( Δ S vap = Δ H vap / T , where T is in K) Compound Name Bp( ?C) Δ H vap (kJ/mol) at bp C 6 H 1 0 O Diethyl ether 34.6 26.5 C 3 H 6 Acetone 56.1 29.1 C 6 H 6 Benzene 79.8 30.8 CHCl 3 Chloroform 60.8 29.4 C 2 H 5 OH Ethanol 77.8 38.6 H 2 O Water 100.0 40.7 All four values should be close to each other. Predict whether the last two liquids in the table have Δ S vap in this same range. If not, predict whether it is larger or smaller and explain. Verify your prediction.
Given the tabulated data, calculate Δ S vap for each of the first four liquids. ( Δ S vap = Δ H vap / T , where T is in K) Compound Name Bp( ?C) Δ H vap (kJ/mol) at bp C 6 H 1 0 O Diethyl ether 34.6 26.5 C 3 H 6 Acetone 56.1 29.1 C 6 H 6 Benzene 79.8 30.8 CHCl 3 Chloroform 60.8 29.4 C 2 H 5 OH Ethanol 77.8 38.6 H 2 O Water 100.0 40.7 All four values should be close to each other. Predict whether the last two liquids in the table have Δ S vap in this same range. If not, predict whether it is larger or smaller and explain. Verify your prediction.
Solution Summary: The author explains the formula used to determine the S v a p values for each compound.
Given the tabulated data, calculate
Δ
S
vap
for each of the first four liquids. (
Δ
S
vap
=
Δ
H
vap
/
T
, where T is in K)
Compound
Name
Bp( ?C)
Δ
H
vap
(kJ/mol) at bp
C6H10O
Diethyl ether
34.6
26.5
C3H6
Acetone
56.1
29.1
C6H6
Benzene
79.8
30.8
CHCl3
Chloroform
60.8
29.4
C2H5OH
Ethanol
77.8
38.6
H2O
Water
100.0
40.7
All four values should be close to each other. Predict whether the last two liquids in the table have
Δ
S
vap
in this same range. If not, predict whether it is larger or smaller and explain. Verify your prediction.
3. (12) Provide the major organic product(s) for the following reactions. Include relevant stereochemistry.
trace HC1
H
HO
+
OH
NH2
x
NH₂
H2SO4
COUN
OH 1. NH2NH2/ H
2. KOH/H₂O/A
O
3. H3O*
H3O+
A
2. (4) Starting with cyclohexanone and using any other reagents as appropriate, write the chemical
equations including structures for a complete stepwise conversion:
O
OH
+ enantiomer
Draw the structure of the major alkene product of the following Wittig reaction. Be sure to indicate the stereochemistry of the alkene.
Q
H
Ph¸P
Click and drag to start drawing a
structure.
G
:
חי
☑
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY