Birefringence
Birefringence is the property of showing more than one refractive index as a function of particle orientation and wavelength.
Such a particle will exhibit interference colors when viewed between crossed circular polarized filters. They will typically show
extinction positions (see below) with rotation of the stage when viewed between crossed linear polarizing filters.
. . . Low Birefringence
. . . Moderate Birefringence
. . . High Birefringence
. . . Anomalous Birefringence
Anomalous birefringence is the result of birefringence varying by wavelength. The result is anomalous interference colors. Silicon
carbide and crocidolite asbestos are two common examples. Crocidolite has higher birefringence in red light (longer Wavelengths) than in
blue. As a result, very thin fibers of crocidolite appear red between crossed polarizing filters. Thicker fibers appear blue because of
the strong blue color of the mineral.
Silicon carbide has higher birefringence in blue light (Shorter Wavelenghts) than in red. As a result, blue wavelengths cycle more
rapidly than red wavelengths. Yellow interference color begins for thinner particles and first order red appears purple because blue
is increasing well before red significantly decreases. This effect changes the color sequence through the whole range of microscopic
silicon carbide particles.
. . . Stress Birefringence
When a material is placed under stress the distribution of the electrons in the material is changed. The amount of change is different for each
material and is a characteristic of the material. The photoelastic constant of the matrial is a measure of the electron displacement (strain) as a
function of the load (stress) applied as long as the deformation is elastic, springs back when the load is removed. If the Young's Modulus of the
matrial is exceeded, then some of the deformation becomes permenant. In some materials the applied load can be "frozen" in place, as in the case of
high stress glass sheet. Polarized light can make the displacement visible. Both plastic deformation and elastic deformation result in an
anisotropic distribution of electrons in the material that becomes visible as interference colors when the object is viewed between crossed linear or
crossed circular polarizing filters. Click on the photographs below for more information.
. . . . . . Stress Birefringence in Skin Cells
. . . . . . Stress Birefringence in Safety Glass
. . . Conductivity Birefringence (Hall Effect?)
Polarized light is depolarized at the interface between a conductive particle and a non-conductive mounting medium. This light halo effect with
transmitted crossed polarized light indicates an opaque particle is a wear metal particle or at least is conductive. Graphite is sufficiently conductive
to produce this effect. Pencil debris can be distinguished from combustion residue by this effect.
. . . . . . Fretting Metal Wear
. . . . . . Graphite
. . . . . . Magnetite Spheres
. . . Form Birefringence
. . . False Birefringence
If the refractive index of a transparent particle is much different than the medium in contact with it, then the polarized beam can be
changed at the interface as a result of reflection. If the interface is aligned with the polarizer or analyzer then the beam is not
affected. In other orientations reflection at the interface results in rotation of the polarized beam and the interface appears to show
a first order white interference color.
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