Coheed & Cambria have been able to blend prog rock and post-hardcore music seamlessly together to create some intricately layered and dense sounds; along with Tool and The Mars Volta (the only other bands I can think of that do that, post-millennium), they have created a music that's both rhythmically complex yet totally listenable- I've always thought that Coheed is what Rush would sound like if they were born way later and were raised on Fugazi and NoMeansNo.
Anyway, here's their debut record from '02; where it lacks in technical prowess it makes up for in raw emotionality.