Fire

Fire is the rapid oxidation of a material in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. Slower oxidative processes like rusting or digestion are not included by this definition. Fire is hot because the conversion of the weak double bond in molecular oxygen to the stronger bonds in the combustion products carbon dioxide and water releases energy. At a certain point in the combustion reaction, called the ignition point, flames are produced. The flame is the visible portion of the fire. Flames consist primarily of carbon dioxide, water vapor, oxygen and nitrogen. If hot enough, the gases may become ionized to produce plasma. Depending on the substances alight, and any impurities outside, the color of the flame and the fire's intensity will be different.

Chemistry

fire tetrahedron

Fires start when a flammable or a combustible material, in combination with a sufficient quantity of an oxidizer such as oxygen, is exposed to a source of heat temperature above the flash point for the fuel mix, and is able to sustain a rate of rapid oxidation that produces a chain reaction. This is commonly called the fire tetrahedron. Fire cannot exist without all of these elements in place and in the right proportions. For example, a flammable liquid will start burning only if the fuel and oxygen are in the right proportions. Some fuel-oxygen mixes may require a substance that is not consumed, when added, in any chemical reaction during combustion, but which enables the reactants to combust more readily.

Once ignited, a chain reaction must take place whereby fires can sustain their own heat by the further release of heat energy in the process of combustion and may propagate, provided there is a continuous supply of an oxidizer and fuel.

If the oxidizer is oxygen from the surrounding air, the presence of a force of gravity, or of some similar force caused by acceleration, is necessary to produce convection, which removes combustion products and brings a supply of oxygen to the fire. Without gravity, a fire rapidly surrounds itself with its own combustion products and non-oxidizing gases from the air, which exclude oxygen and extinguish the fire. Because of this, the risk of fire in a spacecraft is small when it is coasting in inertial flight. This does not apply if oxygen is supplied to the fire by some process other than thermal convection.

Flame

lit candle

A flame is a mixture of reacting gases and solids emitting visible, infrared, and sometimes ultraviolet light. The frequency spectrum of which depends on the chemical composition of the burning material and intermediate reaction products. This light has a continuous spectrum. Complete combustion of gas has a dim blue color due to the emission of single-wavelength radiation from various electron transitions in the excited molecules formed in the flame. Usually oxygen is involved, but hydrogen burning in chlorine also produces a flame, producing hydrogen chloride (HCl). Other possible combinations producing flames are fluorine and hydrogen, and hydrazine and nitrogen tetroxide. Hydrogen and hydrazine flames are similarly pale blue evaluated in mid-20th century as a high energy fuel for jet and rocket engines, emits intense green flame, leading to its informal nickname of "Green Dragon".

The glow of a flame is complex. Black-body radiation is emitted from soot, gas, and fuel particles, though the soot particles are too small to behave like perfect blackbodies. Much of the radiation is emitted in the visible and infrared bands. The color depends on temperature for the black-body radiation, and on chemical makeup for the emission spectra. The dominant color in a flame changes with temperature. Near the ground, where most burning is occurring, the fire is white, the hottest color possible for organic material in general, or yellow. Above the yellow region, the color changes to orange, which is cooler, then red, which is cooler still. Above the red region, combustion no longer occurs, and the uncombusted carbon particles are visible as black smoke.

The common distribution of a flame under normal gravity conditions depends on convection, as soot tends to rise to the top of a general flame, as in a candle in normal gravity conditions, making it yellow. In micro gravity or zero gravity, such as an environment in outer space, convection no longer occurs, and the flame becomes spherical, with a tendency to become more blue and more efficient. There are several possible explanations for this difference, of which the most likely is that the temperature is sufficiently evenly distributed that soot is not formed and complete combustion occurs.

Human control

man making fire

The ability to control fire was a dramatic change in the habits of early humans. Making fire to generate heat and light made it possible for people to cook food, simultaneously increasing the variety and availability of nutrients and reducing disease by killing organisms in the food. The heat produced would also help people stay warm in cold weather, enabling them to live in cooler climates. Fire also kept nocturnal predators at bay.

By the Neolithic Revolution, during the introduction of grain-based agriculture, people all over the world used fire as a tool in landscape management. These fires were typically controlled burns or "cool fires", as opposed to uncontrolled "hot fires", which damage the soil. Hot fires destroy plants and animals, and endanger communities. This is especially a problem in the forests of today where traditional burning is prevented in order to encourage the growth of timber crops. Cool fires are generally conducted in the spring and autumn. They clear undergrowth, burning up biomass that could trigger a hot fire should it get too dense. They provide a greater variety of environments, which encourages game and plant diversity. For humans, they make dense, impassable forests traversable. Another human use for fire in regards to landscape management is its use to clear land for agriculture. Slash-and-burn agriculture is still common across much of tropical Africa, Asia and South America. "For small farmers, it is a convenient way to clear overgrown areas and release nutrients from standing vegetation back into the soil," said Miguel Pinedo-Vasquez, an ecologist at the Earth Institute’s Center for Environmental Research and Conservation. However this useful strategy is also problematic. Growing population, fragmentation of forests and warming climate are making the earth's surface more prone to ever-larger escaped fires. These harm ecosystems and human infrastructure, cause health problems, and send up spirals of carbon and soot that may encourage even more warming of the atmosphere – and thus feed back into more fires. There are numerous modern applications of fire. In its broadest sense, fire is used by nearly every human being on earth in a controlled setting every day. Users of internal combustion vehicles employ fire every time they drive. Thermal power stations provide electricity for a large percentage of humanity.

Video

What Is Fire?