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To do that easily, you can use Newtonsoft.

// To convert an XML node contained in string xml into a JSON string   
XmlDocument doc = new XmlDocument();
doc.LoadXml(xml);
string jsonText = JsonConvert.SerializeXmlNode(doc);

// To convert JSON text contained in string json into an XML node
XmlDocument doc = JsonConvert.DeserializeXmlNode(json);

You can get more info from here.