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SOLVED:The ESI mass spectrum (positive mode) of the ligand shown below exhibits two peaks at m / z 299.2 (base peak) and 321.1 . (a) What is a 'base peak'? (b) Suggest how the observed peaks arise. [Data: C.J. Sumby et al. (2009) Tetrahedron, vol. 65, p. 4681.] CAN'T COPY THE FIGURE

SOLVED:The ESI mass spectrum (positive mode) of the ligand shown below exhibits two peaks at m / z 299.2 (base peak) and 321.1 . (a) What is a 'base peak'? (b) Suggest how the observed peaks arise. [Data: C.J. Sumby et al. (2009) Tetrahedron, vol. 65, p. 4681.] CAN'T COPY THE FIGURE

SOLVED: 7) Electrospray molecular ion mass determination: The ESIspectrum of a protein gives the following m/z values for adjacentpeaks: 1182 and 1290. Use these data to determine the charge numberfor each peak, and the molecular mass of this species. Assume thecharge is due to protonation and use 1.00 for the mass of aproton.

SOLVED: 7) Electrospray molecular ion mass determination: The ESIspectrum of a protein gives the following m/z values for adjacentpeaks: 1182 and 1290. Use these data to determine the charge numberfor each peak, and the molecular mass of this species. Assume thecharge is due to protonation and use 1.00 for the mass of aproton.

PPT - ESI-MS: Electrospray Ionization Mass Spectrometry PowerPoint Presentation - ID:1463957

PPT - ESI-MS: Electrospray Ionization Mass Spectrometry PowerPoint Presentation - ID:1463957

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Problem: Build an ESI-MS spectrum in a) positive and b) negativ... | Filo

Problem: Build an ESI-MS spectrum in a) positive and b) negativ... | Filo

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